抄録
The synthesis and characterization of sulfinate addition-responsive fluorescent molecules are described. We found that addition reaction of sulfinates to naphthalimide-substituted azocarboxylates afforded the corresponding sulfonyl hydrazides with high fluorescence quantum yields (up to 0.91 in THF and 0.54 in methanol), which exhibited a large Stokes shift (105 nm) in protic methanol solvent, while the unsubstituted hydrazide and the sulfonyl-position isomer showed no fluorescence in polar solvents.
本文言語 | 英語 |
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論文番号 | e202400145 |
ジャーナル | Chemistry - An Asian Journal |
巻 | 19 |
号 | 9 |
DOI | |
出版ステータス | 出版済み - 2024/05/02 |
ASJC Scopus 主題領域
- 生化学
- 化学一般
- 有機化学