Abstract
This paper presents the synthesis and characterization of (TMS-ethynyl)-substituted germa[4]pericyclyne composed of acetylene moieties and germanium atoms. Characterization was performed by X-ray crystallography, UVvis absorption, and photoluminescence spectroscopy. DFT calculations suggested interactions between the side chain alkynes and the ringforming acetylenes through germanium vertex atoms.
Original language | English |
---|---|
Pages (from-to) | 782-784 |
Number of pages | 3 |
Journal | Chemistry Letters |
Volume | 45 |
Issue number | 7 |
DOIs | |
State | Published - 2016 |
Keywords
- Element-blocks
- Germanium
- Pericyclynes
ASJC Scopus subject areas
- General Chemistry