Surface morphology of CeO 2 thin films grown on glass substrate from aqueous solution and their optical property

A. Saiki*, C. Kawai, T. Hashizume, K. Terayama

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

1 Scopus citations

Abstract

In this study CeO 2 precursor thin films were deposited onto glass substrates at a room temperature from an aqueous solution by applying constant electrical field and their optical properties were investigated. The precursor was an aqueous solution of Ce(NO 3) 3-6H 2O, M(NO 3) 3-6H 2O (M:Gd,Sm.Y), and NH 3(aq). The thin film was deposited on the glass substrate of the minus electrode side. By applying the electrical field of 2.6-3.6 V, the Ce(OH) 3 thin film was effectively deposited on glass substrates at room temperature. The as-deposited film was amorphous, and a crystalline phase of CeO 2 can be obtained after annealing at 823 K for 5 h in air. Spectral transmission curves of visible to ultraviolet light region through CeO 2 films were measured and about 10 to 30 % absorption peaks were observed around 310 to 330 nm. The relation between growth conditions, surface morphology and their interceptor properties of ultraviolet light region were studied.

Original languageEnglish
Pages (from-to)211-213
Number of pages3
JournalJournal of the Australian Ceramic Society
Volume48
Issue number2
StatePublished - 2012

Keywords

  • Aqueous solution
  • Ceria
  • Dehydration
  • Electro-chemical deposition
  • Optical property
  • Thin film
  • UV light

ASJC Scopus subject areas

  • Ceramics and Composites
  • Materials Chemistry

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