TY - JOUR
T1 - Remarkable Improvement of Organic Photoreaction Efficiency in the Flow Microreactor by the Slug Flow Condition Using Water
AU - Nakano, Momoe
AU - Nishiyama, Yasuhiro
AU - Tanimoto, Hiroki
AU - Morimoto, Tsumoru
AU - Kakiuchi, Kiyomi
N1 - Publisher Copyright:
© 2016 American Chemical Society.
PY - 2016/9/16
Y1 - 2016/9/16
N2 - A typical (Paternò-Büchi type) organic photoreaction is examined in flow microreactors. Compared to the results achieved for simple one-layer flow modes, slug flow conditions (with the unreactive reagent composed of organic solution and water) achieve higher efficiency (conversion and yield) irrespective of the light source, concentration, and solvent. Furthermore, remarkably high productivity is also observed when only 5% water is added as an unreactive reagent. This method is broadly applicable for achieving highly efficient organic photoreactions not only in the laboratory, but also on the industrial scale.
AB - A typical (Paternò-Büchi type) organic photoreaction is examined in flow microreactors. Compared to the results achieved for simple one-layer flow modes, slug flow conditions (with the unreactive reagent composed of organic solution and water) achieve higher efficiency (conversion and yield) irrespective of the light source, concentration, and solvent. Furthermore, remarkably high productivity is also observed when only 5% water is added as an unreactive reagent. This method is broadly applicable for achieving highly efficient organic photoreactions not only in the laboratory, but also on the industrial scale.
UR - http://www.scopus.com/inward/record.url?scp=84987906285&partnerID=8YFLogxK
U2 - 10.1021/acs.oprd.6b00181
DO - 10.1021/acs.oprd.6b00181
M3 - 学術論文
AN - SCOPUS:84987906285
SN - 1083-6160
VL - 20
SP - 1626
EP - 1632
JO - Organic Process Research and Development
JF - Organic Process Research and Development
IS - 9
ER -